Title of article
Highly diastereoselective generation of various 3,3-disubstituted allyl boronates for the stereospecific construction of quaternary centers
Author/Authors
Biggs، نويسنده , , Robyn Aryn and Lambadaris، نويسنده , , Maria and Ogilvie، نويسنده , , William W.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
3
From page
6085
To page
6087
Abstract
Single isomer trisubstituted olefins were converted into allyl boron nucleophiles that were condensed with aldehydes to give products containing quaternary centers. The products were obtained in extremely high diastereomeric ratios, a reflection of the stereochemical integrity of the starting materials.
Keywords
Stereochemistry , Trisubstituted olefins , diastereoselective , quaternary carbon
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1891076
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