Title of article :
Bromodifluoromethylation of aromatic Grignard reagents with CF2Br2
Author/Authors :
Shiosaki، نويسنده , , Masahiro and Inoue، نويسنده , , Munenori، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2014
Abstract :
The bromodifluoromethylation of aromatic Grignard reagents having electron-withdrawing groups with dibromodifluoromethane (CF2Br2) was developed. The reaction proceeded to give the corresponding (bromodifluoromethyl)benzene derivatives via a difluorocarbene-mediated mechanism.
Keywords :
Organofluorine compounds , Bromodifluoromethylation , Aromatic Grignard reagents , difluorocarbene , Dibromodifluoromethane
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
