Title of article
Acid- and isobutylene-free synthesis of t-butyl ethers by in situ formation of 2-t-butoxy-1-methylpyridinium triflate
Author/Authors
Salvati، نويسنده , , Anna E. and Hubley، نويسنده , , Christian T. and Albiniak، نويسنده , , Philip A.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
3
From page
7133
To page
7135
Abstract
The title reagent is formed in situ by alkylation of 2-t-butoxypyrine. The subsequent addition of an alcohol substrate leads to the formation of t-butyl ethers without the need for isobutylene gas or acid activators.
Keywords
etherification , protecting groups , nucleophilic substitution , Carbocation intermediate , Oxypyridinium salt
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1893575
Link To Document