Title of article
Observation of the spin-crossover in [Fe(btr)2(NCS)2] · H2O (btr = 4,4′-bis-1,2,4-triazole) with μSR
Author/Authors
Roubeau، نويسنده , , O. and Gubbens، نويسنده , , P.C.M. and Visser، نويسنده , , D. and Blaauw، نويسنده , , M. and Dalmas de Réotier، نويسنده , , P. and Yaouanc، نويسنده , , Gerard A. and Haasnoot، نويسنده , , J.G. and Reedijk، نويسنده , , J. and Sakarya، نويسنده , , S. and Jayasooriya، نويسنده , , U.A. and Cottrell، نويسنده , , S.P. and King، نويسنده , , P.J.C.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
5
From page
177
To page
181
Abstract
The electronic spin transition in [Fe(btr)2(NCS)2] · H2O (btr = 4,4′-bis-1,2,4-triazole) is probed by longitudinal field muon spin relaxation measurements. The μSR spectra could be analyzed with two different components, corresponding to two muon sites. For both components, an increase in magnetic fluctuations is observed at the LS → HS transition, i.e. crossing the spin transition temperature coming from low temperature, if a sufficiently high field is applied. Even below the transition temperature, magnetic fluctuations are still found. For one of the two muon sites, muonium formation is clearly found below the spin-crossover temperature.
Journal title
Chemical Physics Letters
Serial Year
2004
Journal title
Chemical Physics Letters
Record number
1912574
Link To Document