Determining the elemental composition of fuels by bomb calorimetry and the inverse correlation of HHV with elemental composition

This article presents a method to obtain a simplified elemental analysis of an organic sample in which oxygen, nitrogen, and sulphur are lumped. The method uses a bomb calorimeter, water, and ash measurements combined with a numerical procedure based on a generalised equation for predicting higher heating value. By analysing pure organic substances, literature data, and fuels it is demonstrated that the method can provide hydrogen estimates within ±0.7% daf. and carbon and sum of oxygen, nitrogen, and sulphur estimates within ±2% daf. for fuels containing less than 90% ash db., 2% nitrogen daf., and 1% daf. sulphur.