• Title of article

    Laser spectroscopy of porphycene derivatives: a search for proton tunneling in 2,7,12,17-tetra-tert-butylporphycene

  • Author/Authors

    Nosenko، نويسنده , , Yevgeniy and Jasny، نويسنده , , Jan and Pietraszkiewicz، نويسنده , , Marek and Mordzinski، نويسنده , , Andrzej، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2004
  • Pages
    6
  • From page
    331
  • To page
    336
  • Abstract
    We report on laser induced fluorescence (LIF) excitation and UV/UV fluorescence depletion spectra of 2,7,12,17-tetra-tert-butylporphycene (TTPC) in supersonic expansion. The origin of TTPC consists of two bands, separated by 2.4 cm−1. Independent depletion, as well as the different shapes, widths, influence on ND/NH isotope exchange suggest the peculiar nature of the doublet. The results have been described in terms of two different ground state conformers.
  • Journal title
    Chemical Physics Letters
  • Serial Year
    2004
  • Journal title
    Chemical Physics Letters
  • Record number

    1913445