Title of article
Triplet–triplet energy transfer reaction to cis-stilbene: a dual thermal bond activation mechanism
Author/Authors
Lalevee، نويسنده , , Jacques and Allonas، نويسنده , , Xavier and Fouassier، نويسنده , , Jean Pierre، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
4
From page
483
To page
486
Abstract
The behavior of cis-stilbene in nonvertical triplet–triplet energy transfer (NVET) reactions was examined in detail. A quantitative influence of both the single and double bond torsions on the strong NVET character was clearly evidenced by using a thermal activation model. Moreover, this model appears as powerful and remarkably fits the experimental data. The results are supported by quantum chemical DFT calculations.
Journal title
Chemical Physics Letters
Serial Year
2005
Journal title
Chemical Physics Letters
Record number
1913968
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