Author/Authors :
Pardo، نويسنده , , L.C. and Parat، نويسنده , , B. and Barrio، نويسنده , , Pablo M. and Tamarit، نويسنده , , J.Ll. and Lَpez، نويسنده , , D.O. and Salud، نويسنده , , J. and Negrier، نويسنده , , P. and Mondieig، نويسنده , , D.، نويسنده ,
Abstract :
The orientationally disordered stable and metastable mixed crystals of the two-component system (CH3)CCl3 (1,1,1-trichloroethane) + CBrCl3(bromotrichloro-methane) have been characterised by means of X-ray powder diffraction and thermal analysis techniques. The thermodynamic assessment coherently reproduces the melting equilibria (the stable [R + L] and the partially metastable [FCC + L]) and provides a coherent set of data for the thermodynamic properties of non-experimentally available phase transitions of pure compounds which agree perfectly with those properties obtained from the pressure–temperature phase diagrams.