Title of article
Non-Franck–Condon behavior in the C 1s photoelectron spectrum of the methane molecule
Author/Authors
Ueda، نويسنده , , K. and Pavlychev، نويسنده , , A. and Kukk، نويسنده , , E. and Hergenhahn، نويسنده , , U. and Yoshida، نويسنده , , H. and Sunami، نويسنده , , T. and Tahara، نويسنده , , F. and Tanaka، نويسنده , , T. and Kitajima، نويسنده , , M. and Tanaka، نويسنده , , H. and De Fanis، نويسنده , , A. and Tamenori، نويسنده , , Y.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
4
From page
33
To page
36
Abstract
Vibrationally resolved carbon 1s photoelectron spectra of methane are measured over a photon energy range between 300 and 480 eV. The intensity ratios of the vibrational components vary significantly, exhibiting a minimum at about 330 eV. The observed non-FC distribution is tentatively explained as a result of the internal inelastic scattering of the photoelectron on valence electrons, which leads to the loss of the photoelectron current that depends on the vibrational excitation of the residual ion.
Journal title
Chemical Physics Letters
Serial Year
2005
Journal title
Chemical Physics Letters
Record number
1915941
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