Title of article
One-color two-photon mass-analyzed threshold ionization spectroscopy of 2-bromopropane
Author/Authors
Wang، نويسنده , , Yanmei and Zhang، نويسنده , , Song and Tang، نويسنده , , Bifeng and Zheng، نويسنده , , Qiusha and Zhang، نويسنده , , Bing، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
5
From page
101
To page
105
Abstract
One-color two-photon mass-analyzed threshold ionization has been applied to 2-bromopropane (2-BP). The adiabatic ionization potential energies for the two spin states of this molecule are determined to be 81 403 ± 5 and 83 399 ± 5 cm−1, respectively. A few characteristic vibrations of the 2-BP cation are observed and assigned, which are mainly related to the C–Br stretching and CH3 motions. The C–Br bond is weakened due to the large lengthening of C–Br bond in the cationic state relative to the ground state of the neutral. These results are well supported by our theoretical calculations.
Journal title
Chemical Physics Letters
Serial Year
2005
Journal title
Chemical Physics Letters
Record number
1916141
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