Title of article :
Synthesis, structure and optical limiting property of CoII, MnII and CdII complexes with di-Schiff base and reduced di-Schiff base ligands
Author/Authors :
Kong، نويسنده , , Ling-Yan and Li، نويسنده , , Zhen-Wu and Okamura، نويسنده , , Taka-aki and Ma، نويسنده , , Guo-Hong and Chu، نويسنده , , Qian and Zhu، نويسنده , , Hui-Fang and Tang، نويسنده , , Sing-Hai and Sun، نويسنده , , Wei-Yin and Ueyama، نويسنده , , Norikazu، نويسنده ,
Abstract :
Three coordination polymers [Co(L)2(SCN)2] (1), [Mn(L)2(SCN)2] (2) and [Cd(H4L)2Cl2] (3), were obtained by the reaction of CoII, MnII, CdII salts with di-Schiff base ligand N,N′-bis(3-pyridylmethyl)-4,4′-biphenylenedimethyleneimine (L) and its reduced form (H4L), respectively and their structures were determined by X-ray crystallography. In the solid state, complexes 1 and 2 feature 1D hinged chains, while complex 3 has a 2D network structure. Complex 2 was found to show optical limiting property with a 3 ns pulsed laser at 532 nm in DMF solution.
