Author/Authors :
Piechowska-Strumik، نويسنده , , Katarzyna and Bacchus-Montabonel، نويسنده , , Marie-Christine and Tergiman، نويسنده , , Yvette Suzanne and Sienkiewicz، نويسنده , , Jozef E.، نويسنده ,
Abstract :
Ab initio potential energy surfaces and radial coupling matrix elements of the vinoxy radical have been calculated in a subspace of two active angles involved in the photodissociation process. A quasidiabatic scheme has been developed in the vicinity of the conical intersection and some implications on the possible photodissociation mechanism of vinoxy from different formation path have been discussed.
