Author/Authors :
Hu، نويسنده , , Xingbang and Li، نويسنده , , Haoran and Wang، نويسنده , , Congmin and Han، نويسنده , , Shijun، نويسنده ,
Abstract :
The activating process of O2 on all-metal aromatic complex surface is investigated for the first time by studying the absorption processes of O2 to the surface of Al4Ca and studying the electron configuration of the most stable six Al4CaO2 isomers. It was found that Al4 plane have a special ability to change the electron configuration of O2. As a result, the O2 absorbed on the surface of Al4Ca shows similar character to that of the active oxygen ion 1 O 2 2 - , which may give a base for the future research on the potential catalysis of all-metal aromatic system.
