Resonant neutral-particle emission after collisions of electrons with base-stacked oligonucleotide cations in a storage ring

Electron-cation collisions have been studied for various protonated deoxyoligonucleotide monocations, using an electrostatic storage ring equipped with a merged-electron-beam device. Resonant neutral-particle emissions have been observed at a collision energy of about 4.5 eV for some of them. The resonance parameters depend on DNA base composition and sequence, and the resonances occur only in oligonucleotide monocations with base stacking. The resonance widths increase with oligonucleotide length, but saturate at trimers. Quantum-chemical estimations performed here help explain these results.