Author/Authors :
Lee، نويسنده , , Ying-Chi and Venkatesan، نويسنده , , V. and Lee، نويسنده , , Yuan-Pern and Macko، نويسنده , , P. and Didiriche، نويسنده , , K. R. herman، نويسنده , , M.، نويسنده ,
Abstract :
In spectra of jet-cooled C2H2 recorded with an FTIR spectrometer, the ν5, ν4 + ν5, ν3 and ν2 + ν4 + ν5 bands all exhibit an intensity distribution corresponding to ∼6 K for rotation, with no evidence of nuclear spin conversion. Spectra of C2H2 isolated in solid p-H2 show no evidence of rotation of C2H2. The strong interaction between ν3 and ν2 + ν4 + ν5 in the gas phase is diminished in solid p-H2. Lines associated with dimer, trimer and tetramer of C2H2 are identified. Spectral features characteristic of solid state acetylene are observed under jet-cooled conditions.
