Title of article :
Dependences of molar volumes in solids, partial molal and hydrated ionic volumes of alkali halides on covalent and ionic radii and the golden ratio
Author/Authors :
Heyrovska، نويسنده , , Raji، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2007
Pages :
7
From page :
287
To page :
293
Abstract :
New linear dependences are presented here for the volumes of alkali halides in crystals and in aqueous solutions: (1) the molar volumes in solids ( V B o ) and the partial molal volumes ( ϕ V o ) in aqueous solutions on the sums of crystal ionic volumes, V(M+, X−)cr, (2) ϕ V o on V B o , (3) ϕ V o on the sum of aqueous ionic volumes, V(M+, X−)aq and (4) ϕ V o , V B o , V(M+, X−)cr, V(M+, X−)aq and volume sum of the hydrated ions, ϕ V o ( M + , X - ) h on the sum of atomic volumes V(M, X)cov based on covalent radii. All ionic radii are based on the Golden ratio. The volumes due to electrostriction and ionic hydration have also been estimated.
Journal title :
Chemical Physics Letters
Serial Year :
2007
Journal title :
Chemical Physics Letters
Record number :
1921401
Link To Document :
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