• Title of article

    Heavy mass effect on excited-state double-proton transfer in the 7-azaindole dimer by Cl substitution

  • Author/Authors

    Zhang، نويسنده , , Xuan and Komoto، نويسنده , , Yusuke and Sakota، نويسنده , , Kenji and Nakagaki، نويسنده , , Masayuki and Nakano، نويسنده , , Haruyuki and Shinmyozu، نويسنده , , Teruo and Sekiya، نويسنده , , Hiroshi، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2007
  • Pages
    5
  • From page
    176
  • To page
    180
  • Abstract
    The measurement of the electronic spectra of jet-cooled 4-chloro-7-azaindole dimer (4CAI2) revealed that the Cl substitution substantially suppresses the excited-state double-proton transfer (ESDPT). Quantum chemistry calculation at the CIS level suggested that the change in the intermolecular stretching mode, which promotes ESDPT, is important for the suppression of ESDPT.
  • Journal title
    Chemical Physics Letters
  • Serial Year
    2007
  • Journal title
    Chemical Physics Letters
  • Record number

    1922009