• Title of article

    Photoactivation mechanism of orthovanadate-like (V=O)O3 species

  • Author/Authors

    Teramura، نويسنده , , Kentaro and Hosokawa، نويسنده , , Tomohiro and Ohuchi، نويسنده , , Tai and Shishido، نويسنده , , Tetsuya S. Tanaka، نويسنده , , Tsunehiro، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2008
  • Pages
    4
  • From page
    478
  • To page
    481
  • Abstract
    The photoluminescence spectrum and action spectrum for the photooxidation of orthovanadate-like (V=O)O3 species exhibiting photoluminescence at 520 nm indicate that the triplet excited state T1 of the orthovanadate-like species, which is formed from the singlet excited states S1 and S2 by intersystem crossing, is directly involved in the photooxidation of cyclohexane into cyclohexanone in the presence of molecular oxygen.
  • Journal title
    Chemical Physics Letters
  • Serial Year
    2008
  • Journal title
    Chemical Physics Letters
  • Record number

    1924589