The dissociative recombination of – a saga coming to an end?

Major progress has been made in the understanding of how H 3 + recombines with thermal and sub-thermal electrons, a process of great importance to the chemistry of diffuse interstellar clouds. Two independent ion storage ring experiments with rovibrationally cold H 3 + ions are in excellent agreement, and quantum mechanical calculations agree with the storage ring results quantitatively for the thermal rate constant, if not in all details concerning the cross section. The recombination mechanism is understood. A direct consequence of this progress is that the cosmic-ray ionization rate in diffuse clouds must be shifted upwards to a value larger than 10−16 s−1.