• Title of article

    Transient spectroscopy of UV excited flavone: Triplet–triplet absorption and comparison with theory

  • Author/Authors

    Engler، نويسنده , , Gernot and Nispel، نويسنده , , Michael and Marian، نويسنده , , Christel and Kleinermanns، نويسنده , , Karl، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2009
  • Pages
    4
  • From page
    167
  • To page
    170
  • Abstract
    We reinvestigated the stationary singlet absorption spectrum of flavone and its transient triplet spectrum at excitation wavelengths of 266 and 355 nm in cyclohexane as solvent. The S0–Sn spectra obtained by Density Functional/Multi Reference Configuration Interaction (DFT/MRCI) calculations agree well with experiment. The calculated intense T1–Tn transitions qualitatively reproduce the experimental band maxima observed at ∼330, 365 and 600 nm in cyclohexane.
  • Journal title
    Chemical Physics Letters
  • Serial Year
    2009
  • Journal title
    Chemical Physics Letters
  • Record number

    1926375