Author/Authors :
Wang، نويسنده , , Yi-Hsieh and Teranishi، نويسنده , , Y. and Mineo، نويسنده , , H. and Chao، نويسنده , , S.D. and Selzle، نويسنده , , H.L. and Neusser، نويسنده , , H.J. and Schlag، نويسنده , , E.W. and Lin، نويسنده , , S.H.، نويسنده ,
Abstract :
A main purpose of this Letter is to show how to employ the inverse Born–Oppenheimer approximation as a basis set to study zero kinetic energy (ZEKE) spectroscopy and the autoionization dynamics of the ZEKE states. The calculations of channel couplings, quantum defects, intensity borrowing, vibrational and rotational autotionizations will be demonstrated by using a homonuclear diatomic molecule as an example.
