Title of article
Mass action in ionic solutions
Author/Authors
Eisenberg، نويسنده , , Bob، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
6
From page
1
To page
6
Abstract
The law of mass action describes reactants as simple ideal fluids of concentrations of uncharged noninteracting particles. Ionic solutions contain interacting charged particles and are not ideal. Interactions of reactants can then be mistaken for complexities in chemical reactions or enzymatic catalysts. The variational theory of complex fluids describes flowing mixtures like biological solutions. When a component is added, the theory derives—by mathematics alone—a new set of differential equations that automatically captures all interactions. A variational theory of ionic solutions (as complex fluids) provides computable description of ions in solutions and proteins. Numerical inefficiencies have delayed experimental verification.
Journal title
Chemical Physics Letters
Serial Year
2011
Journal title
Chemical Physics Letters
Record number
1931571
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