• Title of article

    Direct observation of denitrogenation process of 2,3-diazabicyclo[2.2.1]hept-2-ene (DBH) derivatives, using a visible 5-fs pulse laser

  • Author/Authors

    Abe، نويسنده , , Manabu and Iwakura، نويسنده , , Izumi and Yabushita، نويسنده , , Atushi and Yagi، نويسنده , , Shingo and Liu، نويسنده , , Jun and Okamura، نويسنده , , Kotaro and Kobayashi، نويسنده , , Takayoshi، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2012
  • Pages
    5
  • From page
    79
  • To page
    83
  • Abstract
    The mechanism of denitrogenation for 2,3-diazabicyclo[2.2.1]hept-2-ene (DBH) derivatives was investigated using a visible 5-fs pulse laser. The time-dependent wavenumber changes observed in this study revealed that the concerted denitrogenation occurs in the parent DBH. However, a stepwise denitrogenation mechanism was found for the 7,7-diethoxy-substituted DBH derivative.
  • Journal title
    Chemical Physics Letters
  • Serial Year
    2012
  • Journal title
    Chemical Physics Letters
  • Record number

    1932721