Title of article
Oxygen-assisted enhancement of H atom UV-photogeneration from hydrocarbons in van der Waals complexes RH–O2
Author/Authors
Baklanov، نويسنده , , Alexey V. and Bogomolov، نويسنده , , Alexandr S. and Chikishev، نويسنده , , Leonid M. and Bogdanchikov، نويسنده , , Georgii A. and Kochubei، نويسنده , , Sergei A.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
6
From page
25
To page
30
Abstract
The strong enhancement of H-atom UV-photogeneration is revealed in van der Waals complexes of unsaturated hydrocarbons RH (RHethylene C2H4, propylene C3H6, butadiene C4H6, butene–2 C4H8) with oxygen RH–O2 as compared with the ‘free’ RH molecules. The results obtained indicate enhancement of H atom yield to be due to one-quantum photoprocess 1RH–3O2 + hν → 3RH∗ + 3O2(1O2) providing triplet RH molecules with excitation level sufficient for dissociation.
Journal title
Chemical Physics Letters
Serial Year
2013
Journal title
Chemical Physics Letters
Record number
1934382
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