Author/Authors :
Molina، نويسنده , , M.J. and Colussi، نويسنده , , A.J. and Molina، نويسنده , , L.T. and Schindler، نويسنده , , R.N. and Tso، نويسنده , , T.-L.، نويسنده ,
Abstract :
The production of Cl atoms in the laser flash photolysis of ClOOCl at 308 nm has been investigated by time-resolved atomic resonance fluorescence at 235 K. A value of ϕ = 1.03 ± 0.12 has been obtained for the primary quantum yield based on an absorption cross section ratio σ245/σ308 = 22 for ClOOCl at 245 and 308 nm.