Author/Authors :
Kellerman، نويسنده , , D. and Medvedeva، نويسنده , , N. and Mukhina، نويسنده , , N. P. Semenova، نويسنده , , A. and Baklanova، نويسنده , , I. and Perelyaeva، نويسنده , , L. and Gorshkov، نويسنده , , V.، نويسنده ,
Abstract :
The samples of pure and 10% vanadium-doped LiMnPO4 have been synthesized by the solid-state reaction technique. The results of Raman and infrared absorption spectroscopy show that the vanadium atoms replace phosphorus giving rise to LiMn(PO4)1−x(VO4)x solid solutions. This conclusion is confirmed by the first-principle studies.