Title of article
Local structural investigations and speciation of uranium in Sr2P2O7 by time resolved emission spectroscopy and Sr K-edge EXAFS
Author/Authors
Mohapatra، نويسنده , , M. and Yadav، نويسنده , , A.K. and Jha، نويسنده , , S.N. and Bhattacharyya، نويسنده , , D. and Godbole، نويسنده , , S.V. and Natarajan، نويسنده , , V.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2014
Pages
6
From page
81
To page
86
Abstract
To probe the speciation and local structure around the uranium atom in strontium pyrophosphate, time resolved emission and Sr K edge EXAFS study was done. From the photoluminescence data it was observed that uranium was present as uranyl at two different sites. By performing time resolved luminescence, the two uranyl species could be identified. From the EXAFS data it was observed that on doping with uranium, the average Sr–O and Sr–P bond lengths increased. The correlation between the EXAFS and luminescence data confirmed the incorporation of the actinide ion at regular lattice positions of Sr ion in the pyrophosphate matrix.
Journal title
Chemical Physics Letters
Serial Year
2014
Journal title
Chemical Physics Letters
Record number
1936592
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