Title of article :
The synthesis of NH4Zr2F9 and its conversion to ZrO2
Author/Authors :
Lin، نويسنده , , Feng-Qiang and Dong، نويسنده , , Wensheng and Liu، نويسنده , , Chun-Ling and Li، نويسنده , , Men-Yuan، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2009
Abstract :
Rosette-like ammonium flurorzirconate (NH4Zr2F9) aggregates have been synthesized via a novel reaction route by using zirconium oxychloride, urea, 1-butyl-3-methylimidazolium tetrafluoroborate (BMImBF4) and hydrochloric acid in ethanol solution. The as-synthesized NH4Zr2F9 can be changed from rosette-like aggregates to hexagonal plates by varying synthesis conditions. Upon calcination at high temperature NH4Zr2F9 transforms from relative dense structure into highly porous ZrO2 with similar morphology consisting of interconnected nanocrystallites.
Keywords :
Ammonium flurorzirconate , Zirconia , Ionic liquids
Journal title :
Colloids and Surfaces A Physicochemical and Engineering Aspects
Journal title :
Colloids and Surfaces A Physicochemical and Engineering Aspects
