Determination of trace and minor elements in Slovenian honey by total reflection X-ray fluorescence spectroscopy

Trace and minor elements in Slovenian honey were analysed by total reflection X-ray fluorescence spectroscopy. Upto 16 elements (K, Cl, S, P, Ca, Mn, Rb, Cu, Fe, Ni, Cr, Br, Ti, Pb, Sr and As) were detected, in a range of average content from 1.24 mg kg−1 for Sr to 2590 mg kg−1 for K. Statistically significant differences were established between different types of honey (acacia, floral, lime, chestnut, spruce, fir, forest and Metcalfa pruinosa honeydew honey). The highest content of elements was determined in forest honey and the lowest in acacia honey. Honeys were also separated according to their botanical origin as nectar honey or honeydew honey. Total elemental content and the content of S, Cl, K and Rb in honeydew honey was statistically significantly higher than in nectar honey. Chestnut honey differed in statistically its significantly higher contents of Rb and Ca from nectar and honeydew honeys. The year of honey production proved to have no statistically significant influence on elemental content. A comparison of our data with the literature data showed a relatively large diversity.