Title of article :
Self-assembly of metallosupramolecules directed by (N–H)2⋯SCN-M (M=Co, Ni), C–H⋯π and π–π synthons
Author/Authors :
Takahashi، نويسنده , , Pedro M. and Melo، نويسنده , , Lidervan P. and Frem، نويسنده , , Regina C.G. and Netto، نويسنده , , Adelino V.G. and Mauro، نويسنده , , Antonio E. and Santos، نويسنده , , Regina H.A. and Ferreira، نويسنده , , Janaina G.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2006
Abstract :
This work deals with the synthesis, spectroscopic and structural investigation of pyrazolyl complexes of the type trans-[M(NCS)2(HPz)4] {M=Co (1), Ni (2); HPz=pyrazole}. Single crystal X-ray studies on 1 and 2 reveal the formation of similar supramolecular arrangements derived from self-assembly of monomers linked together through intermolecular N–H⋯SCN hydrogen bonds, C–H⋯π interactions and π–π stacking.
Keywords :
Thiocyanate , Hydrogen bonding , Supramolecular synthon , Co(II) and Ni(II) pyrazolyl complexes , SELF-ASSEMBLY
Journal title :
Journal of Molecular Structure
Journal title :
Journal of Molecular Structure
