Title of article
Synthesis, structure and third-order non-linear optical properties of W/S cluster [Fe(DMF)6][W2(μ2-S)2S4]
Author/Authors
Li، نويسنده , , Yong and Zhang، نويسنده , , Zhaoxia and Li، نويسنده , , Ke-Chang and Song، نويسنده , , Wen-Dong and Cui، نويسنده , , Xiao-Bing and Pan، نويسنده , , Ling-Yun، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
5
From page
102
To page
106
Abstract
The homometal cluster [Fe(DMF)6][W2(μ2-S)2S4] 1 (DMF = dimethylformamide) was successfully synthesized by low-temperature solid-state reactions. X-ray single-crystal diffraction studies reveal that compound 1 is dinuclear anion cluster. The compound was characterized by elemental analyses, IR spectra and UV–vis spectra. The third-order non-linear optical (NLO) properties of the cluster were also investigated and exhibited non-linear rare saturation absorption (α2 < 0) and self-defocusing performance with modulus of the hyperpolarizabilities 9.547 × 10−31 esu for 1.
Keywords
Homometal cluster , solid-state reaction , Third-order non-linear optical properties
Journal title
Journal of Molecular Structure
Serial Year
2007
Journal title
Journal of Molecular Structure
Record number
1964188
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