Title of article
Synthesis, characterization and crystal structure of a new dimeric tetra-Ni-substituted sandwich tungstogermanate
Author/Authors
Zhang، نويسنده , , Zhiming and Wang، نويسنده , , Enbo and Li، نويسنده , , Yangguang and Qi، نويسنده , , Yanfei and Tan، نويسنده , , Huaqiao، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
4
From page
128
To page
131
Abstract
A new tungstogermanate NaK5Ni3(H2O)18[Ni4(H2O)2 (GeW9O34)2] ·13.5H2O (1) has been obtained in aqueous solution and characterized by IR, UV, element analysis, TG, electrochemistry and X-ray single crystal diffraction analysis. Polyoxoanion 1 was composed of two [GeW9O34]10− units linked by a Ni4 cluster, which was first observed, and the anions were connected by K+ ions to constitute a novel one-dimensional chainlike complex.
Keywords
Inorganic polyoxometalate chain , Dimeric polyoxoanion , tungstogermanate , nickel
Journal title
Journal of Molecular Structure
Serial Year
2007
Journal title
Journal of Molecular Structure
Record number
1964193
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