Title of article
A ternary tetracoordinated PdII complex with metformin and dipicolinate: Synthesis, characterization and crystal structure
Author/Authors
Moghimi، نويسنده , , A. and Khavassi، نويسنده , , H.R. and Dashtestani، نويسنده , , F. and Kordestani، نويسنده , , D. and Ekram Jafari، نويسنده , , A. and Maddah، نويسنده , , B. and Moosavi، نويسنده , , S.M.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
4
From page
38
To page
41
Abstract
A proton transfer compound L, (MetH)2(dipic), (dipicH2 = 2,6-pyridinedicarboxylic acid and Met = Metformin (N,N-dimethylebiguanidine), was synthesized and characterized by IR, 1H and 13C NMR spectroscopy. The reaction of L with PdCl2 in water results in the formation of novel tetracoordinated PdII complex [Pd(dipic)(Met)]·2H2O indicating the participation of both dipic2− and Met as chelating ligands. This complex was characterized by single crystal X-ray analysis. The crystal system is monoclinic with space group P21/c. The unit cell dimensions for PdII complex 1 is a = 8.8619(14) Å, b = 9.5072(9) Å, c = 19.153(3) Å.
Keywords
PdII complex , Complex , X-Ray , Metformin , 6-pyridinedicarboxylic acid , 2
Journal title
Journal of Molecular Structure
Serial Year
2011
Journal title
Journal of Molecular Structure
Record number
1970455
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