Title of article :
Syntheses, characterizations and electrochemical properties of mesomorphic 4-(4′-alkoxy-(1,1′-biphenyl)-4-oxy)butane-1-sulfonic acids
Author/Authors :
Tan، نويسنده , , Shuai and Wang، نويسنده , , Caihong and Liang، نويسنده , , Ting and Huang، نويسنده , , Weixing and Wu، نويسنده , , Yong، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2013
Pages :
5
From page :
15
To page :
19
Abstract :
Biphenyl based sulfonic acid derivatives have been synthesized for anhydrous proton conduction. The terminal sulfonic acid moiety was attached to a biphenyl core by ring-opening reaction of 1,4-butane sultone. The target compounds exhibited smectic phases in a temperature range of 180–220 °C. Polarizing optical microscopic observation and temperature dependent X-ray diffraction measurements suggested that sulfonic acid moieties formed a head-to-head configuration in the smectic assemblies. The mesomorphic sulfonic acid derivatives formed lamellar proton conducting pathways and the anhydrous proton conductivities determined by electrochemical impedance spectroscopy showed Arrhenius temperature dependence in the smectic phase.
Keywords :
Sulfonic acid , Mesogen , Smectic mesophase , Bilayer configuration , Electrochemical impedance spectroscopy
Journal title :
Journal of Molecular Structure
Serial Year :
2013
Journal title :
Journal of Molecular Structure
Record number :
1973964
Link To Document :
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