Author/Authors :
Ren، نويسنده , , Shi-Bin and Qiu، نويسنده , , Zhang-Jian and Yan، نويسنده , , Jun and Zhao، نويسنده , , Song-Lin and Wu، نويسنده , , Cheng-Lin and Jia، نويسنده , , Wen Ping and Han، نويسنده , , De-Man and Liang، نويسنده , , Hua-Ding، نويسنده ,
Abstract :
Two new coordination polymers based on CuX (X = SCN, I) and L have been successfully prepared by solvothermal reactions: [Cu4I4L] (1) and [Cu4(SCN)4L] (2) (L = tetrakis(3-pyridyloxymethylene)methane), exhibiting a doubly-fold interpenetrating diamondlike framework for 1 and a noncatenated structure with infinite[Cu(SCN)]n chains for 2. Their structural analysis shows the symmetry matching of their secondary building unit (SBU) can effectively control their degree of interpenetration.
Keywords :
Metal–organic framework , Doubly-fold interpenetrating , Symmetry matching , Noncatenated
