Synthesis, crystal structure and nuclease activity of a Cu(II) complex having two different co-ordination geometries in the same unit cell

A new Cu(II) complex of a Schiff base ligand having N2O donor set has been synthesized and fully characterized through its single crystal X-ray studies. Two different co-ordination patterns viz. square planar and square pyramidal for Cu(II) were observed within the same unit cell. The DNA binding of copper(II) complex was investigated through UV–vis, fluorescence as well as cyclic voltammetric studies. The complex exhibited efficient functional mimicking of nuclease activity over the plasmid pBR322 DNA.