• Title of article

    Development of a Modified Bromleyʹs Methodology (MBM) for the estimation of ionic media effects on solution equilibria. Part 2. Correlation of the molar and molal interaction parameters with the charge and crystal radii of the ions

  • Author/Authors

    Borge، نويسنده , , Gregorio and Etxebarria، نويسنده , , Nestor and Fernلndez، نويسنده , , Luis A. and Olazabal، نويسنده , , Maria A. and Madariaga، نويسنده , , Juan M.، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 1996
  • Pages
    11
  • From page
    99
  • To page
    109
  • Abstract
    The interaction parameters of strong electrolytes obtained for both the molar and molal scales using the Modified Bromleyʹs Methodology (MBM) have been correlated with the ionic charge and individual crystal radius of each ion. The correlation function for each ion with opposite counterions is a straight line centered in the water radius value (1.39 × 10−10m). These correlations allow the prediction of values of unknown interaction parameters of a cation with several anions even if only one interaction parameter of the cation with a given anion is known.
  • Keywords
    Activity Coefficients , Methods of calculation , electrolytes , Chemical equilibria , solutions , Theory
  • Journal title
    Fluid Phase Equilibria
  • Serial Year
    1996
  • Journal title
    Fluid Phase Equilibria
  • Record number

    1980393