Title of article :
Development of a Modified Bromleyʹs Methodology (MBM) for the estimation of ionic media effects on solution equilibria. Part 2. Correlation of the molar and molal interaction parameters with the charge and crystal radii of the ions
Author/Authors :
Borge، نويسنده , , Gregorio and Etxebarria، نويسنده , , Nestor and Fernلndez، نويسنده , , Luis A. and Olazabal، نويسنده , , Maria A. and Madariaga، نويسنده , , Juan M.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 1996
Pages :
11
From page :
99
To page :
109
Abstract :
The interaction parameters of strong electrolytes obtained for both the molar and molal scales using the Modified Bromleyʹs Methodology (MBM) have been correlated with the ionic charge and individual crystal radius of each ion. The correlation function for each ion with opposite counterions is a straight line centered in the water radius value (1.39 × 10−10m). These correlations allow the prediction of values of unknown interaction parameters of a cation with several anions even if only one interaction parameter of the cation with a given anion is known.
Keywords :
Activity Coefficients , Methods of calculation , electrolytes , Chemical equilibria , solutions , Theory
Journal title :
Fluid Phase Equilibria
Serial Year :
1996
Journal title :
Fluid Phase Equilibria
Record number :
1980393
Link To Document :
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