Title of article
Isothermal vapor–liquid equilibrium at 333.15 K, excess molar volumes and refractive indices at 298.15 K for mixtures of tert-amyl methyl ether + ethanol + 2,2,4-trimethylpentane
Author/Authors
Hwang، نويسنده , , In-Chan and Lee، نويسنده , , Jae-Yeon and Park، نويسنده , , So-Jin، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
7
From page
5
To page
11
Abstract
Isothermal vapor–liquid equilibrium data at 333.15 K are measured for the binary system tert-amyl methyl ether + ethanol and tert-amyl methyl ether + 2,2,4-trimethylpentane and for ternary system tert-amyl methyl ether + ethanol + 2,2,4-trimethylpentane by using headspace gas chromatography. The experimental vapor–liquid equilibrium data were correlated with GE models (Margules, van Laar, Wilson, NRTL, UNIQUAC) equations. The excess volume and deviations in molar refractivity data are also reported for the same binary and ternary systems at 298.15 K. These data were correlated with the Redlich–Kister equation for the binary systems and the Cibulka equation for the ternary system, respectively. The experimental ternary excess volume and deviations in molar refractivity data, were also compared with the estimated values from the binary contribution models of Tsao–Smith, Kohler, Rastogi and Radojkovič.
Keywords
Vapor–liquid equilibrium , 2 , Refractive Indices , Ethanol , Excess molar volumes , 4-Trimethylpentane , 2 , tert-Amyl methyl ether
Journal title
Fluid Phase Equilibria
Serial Year
2009
Journal title
Fluid Phase Equilibria
Record number
1987469
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