Title of article :
Determination of the solubility, dissolution enthalpy and entropy of 3-pentadecylphenyl acrylate in methanol–ethanol solutions
Author/Authors :
Liu، نويسنده , , Wei and Xu، نويسنده , , Li and Li، نويسنده , , Yanxun and Luo، نويسنده , , Tingliang and Liu، نويسنده , , Guoji، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2012
Abstract :
The solubilities of 3-pentadecylphenyl acrylate in methanol–ethanol mixture solvents of different compositions were measured at temperatures ranging from 273.15 K to 297.15 K at atmospheric pressure using a laser detecting system. The solubility data were correlated by the modified Apelblat equation and Buchowski–Ksiazczak λh equation. Both the Apelblat equation and the Buchowski–Ksiazczak λh equation can fit the solubility data well. The dissolution enthalpy and entropy of 3-pentadecylphenyl acrylate were predicted with the solubility data using modified Apelblat equation.
Keywords :
Solid–liquid equilibrium , 3-Pentadecylphenyl acrylate , solubility , Dissolution enthalpy , Dissolution entropy
Journal title :
Fluid Phase Equilibria
Journal title :
Fluid Phase Equilibria