Title of article
Solubility of chlocyphos in different solvents
Author/Authors
Sun، نويسنده , , Fengxia and Kang، نويسنده , , Huaiping and Zhang، نويسنده , , Kun and Liu، نويسنده , , Baoshu and Zhang، نويسنده , , Bingzhu، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
5
From page
12
To page
16
Abstract
Chlocyphos is a novel highly acidic and efficient resolving agent. Solubility of chlocyphos in methanol, ethanol, isopropyl alcohol, tert-butyl alcohol, glacial acetic acid and water from 278.15 K to 348.15 K was determined by using a static equilibrium method in this paper. The solubility data of chlocyphos in methanol, ethanol, isopropyl alcohol, tert-butyl alcohol and water were correlated well with modified Apelblat equation, and the experimental data of chlocyphos in glacial acetic acid were correlated well with the Buchowski–Ksiazaczak λh equation. Results of these measurements can be used for purification of chlocyphos and preparation of optical amine obtained by resolution using chlocyphos.
Keywords
Chlocyphos , Solid–liquid equilibrium , solubility , Correlation
Journal title
Fluid Phase Equilibria
Serial Year
2012
Journal title
Fluid Phase Equilibria
Record number
1989143
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