Title of article :
Infinite dilution activity coefficients and Henryʹs law constants of compounds in water using the inert gas stripping method
Author/Authors :
Brockbank، نويسنده , , Sarah A. and Russon، نويسنده , , Jenna L. and Giles، نويسنده , , Neil F. and Rowley، نويسنده , , Richard L. and Wilding، نويسنده , , W. Vincent، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2013
Abstract :
Henryʹs law constants and infinite dilution activity coefficients were measured for toluene, 1-butanol, anisole, 1,2-difluorobenzene, 4-bromotoluene, 1,2,3-trichlorobenzene, and 2,4-dichlorotoluene in water using the inert gas stripping method at ambient pressure (approximately 86.2 kPa) and at temperatures between 281.15 K and 323.15 K. Fugacity ratios, required to determine infinite dilution activity coefficients for the solid solutes, were calculated from literature values for the heat of fusion and the liquid and solid heat capacities. Chemicals were chosen based on missing or conflicting data from the literature.
Keywords :
Henryיs law constant , Infinite dilution activity coefficient , Inert gas stripping
Journal title :
Fluid Phase Equilibria
Journal title :
Fluid Phase Equilibria