Title of article :
Determination and correlation of solubilities of 1,2-bis (2-oxo-5,5-dimethyl-1,3,2-dioxyphosphacyclohexyl-2-imino) ethane in selected solvents
Author/Authors :
Qi ، نويسنده , , Chunmei and Wang، نويسنده , , Li-Sheng and Du، نويسنده , , Jun-Chao and Yu، نويسنده , , Guomin and Sun، نويسنده , , Gui-Qin، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2013
Pages :
8
From page :
343
To page :
350
Abstract :
1,2-Bis (2-oxo-5,5-dimethyl-1,3,2-dioxyphosphacyclohexyl-2-imino) ethane (BPEA) was prepared, and characterized by elemental analysis (EA), mass spectra (MS), infrared spectroscopy (IR) and nuclear magnetic resonance (NMR). The melting point and the enthalpy of fusion of BPEA were performed on differential scanning calorimetry (DSC), and the thermal stability of BPEA was tested by thermogravimetric analysis (TGA). The solubility of BPEA in selected solvents was measured by a static analytical method. The experimental data were correlated with different thermodynamic models, such as the empirical equation and non-random two liquid (NRTL), Wilson, Scatchard–Hildebrand, and universal quasi chemical (UNIQUAC) equations. The calculated results showed good agreement with the experimental data in the temperature range studied.
Keywords :
solubility , Phosphorus–nitrogen compounds , Organic solvents , flame retardant
Journal title :
Fluid Phase Equilibria
Serial Year :
2013
Journal title :
Fluid Phase Equilibria
Record number :
1989750
Link To Document :
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