Author/Authors :
Chernov، نويسنده , , V.A and Ivanova، نويسنده , , V.N and Kozhevnikova، نويسنده , , A.N and Mardezhova، نويسنده , , G.A and Nikitenko، نويسنده , , S.G and Nikiforov، نويسنده , , A.A، نويسنده ,
Abstract :
A series of new organometallic polymers, PdnC60, with varying PdC60 ratios was prepared and studied using EXAFS spectroscopy. The Pd K-edge EXAFS analysis suggests that the Pd atoms act as bridges between adjacent C60 molecules by coordination to the pi-electrons of their double bonds. The distance between the Pd atom and the nearest carbon atoms PdC1 (2.27(3) Å) is found to be somewhat longer than that in typical Pd(O)-elefin pi-complexes.
