Title of article :
Vapor–liquid equilibria for the binary system hexan-1-ol + tert-butyl methyl ether (MTBE) at 298.15, 318.15, and 338.15 K
Author/Authors :
de Llano، نويسنده , , Julieta Jiménez and Segade، نويسنده , , Ana Luisa and Jiménez، نويسنده , , Eulogio and del R??o، نويسنده , , Armando and Renuncio، نويسنده , , Juan A.R. and Pando، نويسنده , , Concepci?n، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
Vapor–liquid equilibrium (VLE) data are reported for the binary mixtures formed by hexan-1-ol and the branched ether tert-butyl methyl ether (MTBE). A Gibbs–van Ness type apparatus was used to obtain total vapor pressure measurements as a function of composition at 298.15, 318.15, and 338.15 K. The system shows positive deviations from Raoult’s law. VLE data are analyzed using the UNIQUAC equation and compared with predictions from the modified UNIFAC (Dortmund) model.
Keywords :
Binary liquid mixtures , vapor pressure , Vapor–liquid equilibria , Branched ether , Gibbs energy
Journal title :
Fluid Phase Equilibria
Journal title :
Fluid Phase Equilibria
