Title of article
Some properties of Nd and Er complexes with 1,2,3,4,5,6-benzenehexacarboxylic (mellitic) acid
Author/Authors
Ostasz، نويسنده , , A. and ?yszczek، نويسنده , , Simcha R. and Mazur، نويسنده , , L. and Sienkiewicz-Gromiuk، نويسنده , , J. and Rusinek، نويسنده , , I. and Rz?czy?ska، نويسنده , , Z.، نويسنده ,
Pages
8
From page
203
To page
210
Abstract
The influence of synthesis conditions on the structural and thermal properties of solid lanthanide 1,2,3,4,5,6-benzenehexacarboxylates (mellitates) was investigated. The general formula of the complexes is Ln2(C12O12)·nH2O (where Ln = Nd(III) and Er(III), n = 10 for Nd, and n = 14 for Er – mild conditions; n = 6 for Nd and Er – hydrothermal synthesis). They were characterized by elemental analysis, X-ray diffraction methods, IR spectroscopy and thermal analysis methods (TG-DSC and TG-FTIR). The prepared complexes are crystalline but not isostructural. The IR spectra confirm deprotonation of all carboxylic groups in all investigated complexes. Their thermal stability as well as pathway of thermal decomposition differ significantly.
Keywords
1 , Mellitates , hydrothermal synthesis , 5 , 3 , 4 , 2 , Lanthanide complexes , 6-Benzenehexacarboxylates
Journal title
Astroparticle Physics
Record number
2036521
Link To Document