STM studies of 1-D noble metal growth on silicon

Our scanning tunneling microscopy (STM) studies show that noble metals (Ag, Au) form a wide variety of 1-D structures on the high-index Si(5 5 12) surface. At coverages below 0.25 monolayer (ML), both metals grow as overlayer rows with an inter-row spacing of ∼5 nm. At higher coverages and annealing temperatures, the underlying Si reconstruction is removed, but periodic row structures persist. Au can also induce faceting to nearby planes, e.g. (7 7 15) and (2 2 5), at temperatures above 500°C. For all coverages and annealing temperatures studied here (0.02–1 ML, 450–800°C), the Si(5 5 12) template initiates 1-D growth of the deposited noble metals.