The oxidation of Fe3Al–(0, 2, 4, 6%)Cr alloys at 1000 °C

Thermomechanically treated Fe3Al–(0, 2, 4, 6at.%)Cr alloys were isothermally oxidized at 1000 °C in air, and their oxidation characteristics were studied using thermogravimetric analyzer, X-ray diffractometer, scanning electron microscope, electron probe microanalyzer, and TEM/EDS. It was found that Cr decreased the oxidation resistance of Fe3Al alloys to a certain extent. The oxide scales that formed on the unalloyed Fe3Al alloys consisted primarily of α-Al2O3 containing a small percentage of dissolved iron ions. Less than 1% of dissolved chromium ions was additionally present in the oxide scale formed on the Fe3Al–Cr alloys. An Al-free, Fe-enriched zone was formed beneath the oxide scale, owing to Al consumption to form the oxide scale. The oxide scale on all alloys had poor adherence.