Author/Authors :
Yu، نويسنده , , Jenwei and Hayashi، نويسنده , , M. and Lin، نويسنده , , S.H. and Liang، نويسنده , , K.-K. and Hsu، نويسنده , , J.H. and Fann، نويسنده , , W.S. and Chao، نويسنده , , Ching-Ian and Chuang، نويسنده , , Kuen-Ru and Chen، نويسنده , , Show-An، نويسنده ,
Abstract :
The experimental temperature-dependent absorption, phololuminescence and photoluminescence excitation spectra of poly (p-phenylenevinylene) (PPV) are presented and a molecular theory is used to analyze the results. In order to model the complicated system such as PPV, the structural inhomogeneity has to be included. The structural inhomogeneity is represented by the different Huang-Rhys factors associated with different chain lengths. The theoretical spectra agree qualitatively with the experimental results.