Author/Authors :
Lapkowski، نويسنده , , M. and Kiebooms، نويسنده , , R. and Pro?، نويسنده , , William A. and Chauvet، نويسنده , , O. and Gelan، نويسنده , , Thomas J. and Vanderzande، نويسنده , , D. and Lefrant، نويسنده , , S.، نويسنده ,
Abstract :
It is demonstrated that the anodic oxidation of 2,5-bis(tert-butyldimethylsilyl) isothianaphthene in Bu4NBF4/nitrobenzene electrolyte results in the formation of poly(isothianaphthene) film with an average polymerization degree of 20. Disilylated isothianaphthene dimer and trimer do not polymerize in this electrolyte giving upon anodic oxidation stable radical cations and dications.
Keywords :
Spectroelectrochemistry , Raman spectroelectrochemistry , Electrochemistry , Poly(isothianaphthene)
