Author/Authors :
Louarn، نويسنده , , G. Zakrzewska-Trznadel، نويسنده , , M. and Zagorska، نويسنده , , M. and Lapkowski، نويسنده , , M. and Pron، نويسنده , , Adam and Buisson، نويسنده , , J.P. and Lefrant، نويسنده , , S.، نويسنده ,
Abstract :
In this work, we present a characterization study of the electronic and vibrational properties of regioregular poly(3-decylthiophene) by means of luminescence, optical absorption and Resonant Raman Scattering (RRS) measurements. Photoluminescence studies carried out with an excitation wavelength of 2.42 eV (514.5 nm) show a luminescence signal characterized by a structured band with a maximum at 2.66 eV. Results obtained by RRS are presented and discussed. By using a dynamical model based on a valence force field, Raman vibrational modes are assigned and a set, of force constants is determined for the polymer
